(N-Phenylthiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate
نویسندگان
چکیده
In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network.
منابع مشابه
Crystal structure of bis(thiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate
In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1)...
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عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014